MassBank Record: MSJ01067



 Acetamiprid; GC-EI-Q; MS; Positive; M+* 
Mass Spectrum
Chemical Structure
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ACCESSION: MSJ01067
RECORD_TITLE: Acetamiprid; GC-EI-Q; MS; Positive; M+*
DATE: 2017.07.13 (2016.12.28)
AUTHORS: , Shimadzu Corporation., Kyoto, Japan
LICENSE: CC BY
COPYRIGHT: Shimadzu Cooperation., Kyoto, Japan
PUBLICATION: Shimadzu Collection of Pesticide GCMS Data

CH$NAME: Acetamiprid CH$COMPOUND_CLASS: Non-Natural Product; Pesticides CH$FORMULA: C10H11ClN4 CH$EXACT_MASS: 222.06722 CH$SMILES: N#CN=C(C)N(C)Cc(c1)cnc(Cl)c1 CH$IUPAC: InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3 CH$LINK: INCHIKEY WCXDHFDTOYPNIE-UHFFFAOYSA-N CH$LINK: PUBCHEM CID:213021
AC$INSTRUMENT: GCMS-QP2010 Plus, Shimadzu AC$INSTRUMENT_TYPE: GC-EI-Q AC$MASS_SPECTROMETRY: MS_TYPE MS AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION EI AC$CHROMATOGRAPHY: COLUMN_NAME Ptx-5MS(RESTEK), 0.32 mm I.D. x 30 m, df=0.25 microm AC$CHROMATOGRAPHY: COLUMN_TEMPERATURE 80 C (1 min)-20 C/min - 180 C - 5 C/min - 330C (10 min) AC$CHROMATOGRAPHY: INJECTION_TEMPERATURE 260 C AC$CHROMATOGRAPHY: RETENTION_TIME 17.0 min
MS$FOCUSED_ION: ION_TYPE [M]+* MS$FOCUSED_ION: PRECURSOR_M/Z 222.07
PK$SPLASH: splash10-0zfu-9800000000-b82c70df6ee48ad132f5 PK$NUM_PEAK: 146 PK$PEAK: m/z int. rel.int. 40 8 8 41 92 92 42 622 622 43 131 131 46 11 11 47 10 10 49 46 46 50 77 77 51 70 70 52 60 60 53 16 16 54 56 56 55 91 91 56 999 999 57 74 74 58 5 5 62 31 31 63 213 213 64 68 68 65 98 98 66 48 48 67 363 363 68 19 19 69 39 39 71 122 122 72 17 17 73 134 134 75 99 99 76 99 99 77 38 38 79 24 24 80 38 38 84 31 31 85 39 39 87 11 11 90 347 347 91 118 118 92 40 40 93 45 45 94 6 6 97 8 8 98 37 37 99 221 221 100 32 32 101 82 82 102 25 25 103 30 30 104 15 15 106 29 29 109 15 15 112 60 60 113 33 33 114 92 92 116 32 32 117 9 9 118 19 19 119 35 35 121 7 7 122 12 12 124 15 15 125 11 11 126 589 589 127 136 136 128 204 204 129 82 82 130 15 15 131 15 15 132 7 7 136 7 7 138 7 7 139 74 74 141 214 214 142 7 7 143 76 76 144 28 28 145 5 5 146 26 26 152 725 725 153 338 338 154 272 272 155 294 294 156 28 28 157 48 48 159 15 15 160 17 17 161 9 9 163 24 24 166 262 262 167 54 54 168 88 88 169 15 15 170 19 19 171 24 24 172 6 6 174 5 5 180 11 11 181 127 127 182 58 58 183 52 52 184 9 9 185 11 11 187 50 50 188 19 19 194 17 17 197 13 13 198 60 60 199 5 5 200 49 49 206 9 9 212 7 7 217 11 11 221 207 207 222 72 72 223 57 57 224 13 13 226 5 5 228 7 7 233 6 6 236 6 6 240 6 6 241 5 5 251 5 5 278 7 7 296 11 11 303 5 5 336 5 5 349 7 7 352 5 5 353 10 10 355 17 17 412 13 13 431 7 7 457 5 5 460 5 5 485 5 5 488 6 6 492 7 7 496 5 5 497 13 13 506 8 8 511 11 11 537 10 10 567 6 6 570 19 19 585 7 7 597 12 12 //