MassBank Record: NGA00963



 Cycloheximide; LC-ESI-QQQ; MS2; Frag=135.0V CID@10.0; [M+H]+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: NGA00963
RECORD_TITLE: Cycloheximide; LC-ESI-QQQ; MS2; Frag=135.0V CID@10.0; [M+H]+
DATE: 2018.04.04
AUTHORS: Nogawa TCSRS, RIKEN, Okano ACSRS, RIKEN, CSRS, RIKEN
LICENSE: BY-CC
COMMENT: Origin: Microbe
COMMENT: SubCategory_DNP: Alkaloids derived from lysine, Piperidine alkaloids

CH$NAME: Cycloheximide CH$COMPOUND_CLASS: Alkaloids CH$FORMULA: C15H23NO4 CH$EXACT_MASS: 281.35486000000003 CH$SMILES: CC1C[C@H](C)C(=O)[C@H]([C@H](O)CC2CC(=O)N=C(O)C2)C1 CH$IUPAC: InChI=1S/C15H23NO4/c1-8-3-9(2)15(20)11(4-8)12(17)5-10-6-13(18)16-14(19)7-10/h8-12,17H,3-7H2,1-2H3,(H,16,18,19)/t8?,9-,11-,12+/m0/s1 CH$LINK: CAS 66-81-9 CH$LINK: PUBCHEM CID:5962 CH$LINK: INCHIKEY YPHMISFOHDHNIV-IDHBKJTRSA-N
AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system AC$INSTRUMENT_TYPE: LC-ESI-QQQ AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
PK$SPLASH: splash10-01ot-0090000000-c5bdd186702d3410eb2d PK$NUM_PEAK: 156 PK$PEAK: m/z int. rel.int. 156.7 2.72 2 156.8 4.35 4 156.9 5.88 5 157.0 6.77 6 157.1 6.91 6 157.2 6.44 6 157.3 5.5 5 157.4 4.1 4 157.5 2.4 2 158.6 1.39 1 158.7 2.81 2 158.8 5.07 5 158.9 7.19 7 159.0 8.23 8 159.1 8.34 8 159.2 8.21 8 159.3 7.81 7 159.4 6.51 6 159.5 4.21 4 159.6 1.74 1 172.8 2.68 2 172.9 4.35 4 173.0 6.39 6 173.1 7.99 7 173.2 8.56 8 173.3 7.91 7 173.4 6.06 6 173.5 3.47 3 182.8 1.74 1 182.9 3.07 3 183.0 4.53 4 183.1 5.32 5 183.2 5.04 5 183.3 4.01 4 183.4 2.75 2 186.7 2.45 2 186.8 4.49 4 186.9 6.54 6 187.0 7.98 7 187.1 8.83 8 187.2 9.07 9 187.3 8.22 8 187.4 5.98 5 187.5 3.1 3 200.7 2.53 2 200.8 4.42 4 200.9 7.07 7 201.0 9.94 9 201.1 11.99 11 201.2 12.34 12 201.3 10.92 10 201.4 8.31 8 201.5 5.16 5 201.6 2.23 2 204.7 2.41 2 204.8 4.32 4 204.9 6.44 6 205.0 8.1 8 205.1 8.96 8 205.2 8.96 8 205.3 8.06 8 205.4 6.18 6 205.5 3.63 3 217.7 1.43 1 217.8 2.82 2 217.9 4.53 4 218.0 5.8 5 218.1 6.2 6 218.2 6.19 6 218.3 6.31 6 218.4 6.35 6 218.5 5.81 5 218.6 5.3 5 218.7 6.31 6 218.8 9.65 9 218.9 14.53 14 219.0 19.29 19 219.1 22.55 22 219.2 23.56 23 219.3 21.88 21 219.4 17.39 17 219.5 11.07 11 219.6 5.1 5 228.6 4.61 4 228.7 5.83 5 228.8 9.58 9 228.9 15.12 15 229.0 20.5 20 229.1 24.15 24 229.2 25.28 25 229.3 23.43 23 229.4 18.51 18 229.5 11.51 11 229.6 4.69 4 229.7 0.62 0 245.2 0.52 0 245.3 2.11 2 245.4 4.82 4 245.5 8.08 8 245.6 12.6 12 245.7 21.26 21 245.8 36.78 36 245.9 58.18 58 246.0 79.94 79 246.1 95.24 95 246.2 100.0 99 246.3 93.64 93 246.4 77.21 77 246.5 53.58 53 246.6 29.85 29 246.8 17.38 17 246.9 29.74 29 247.0 43.21 43 247.1 50.92 50 247.2 51.7 51 247.3 46.29 46 247.4 34.91 34 247.5 19.74 19 247.6 6.36 6 247.7 0.06 0 263.3 1.15 1 263.4 2.96 2 263.5 5.91 5 263.6 10.28 10 263.7 17.61 17 263.8 30.37 30 263.9 48.55 48 264.0 66.91 66 264.1 78.42 78 264.2 80.68 80 264.3 75.83 75 264.4 64.65 64 264.5 46.37 46 264.6 24.97 24 264.9 13.39 13 265.0 22.27 22 265.1 27.95 27 265.2 29.27 29 265.3 27.24 27 265.4 22.36 22 265.5 14.75 14 265.6 6.33 6 265.7 0.6 0 281.5 2.03 2 281.6 3.45 3 281.7 5.71 5 281.8 9.74 9 281.9 16.19 16 282.0 23.94 23 282.1 30.2 30 282.2 32.36 32 282.3 29.75 29 282.4 23.22 23 282.5 14.42 14 282.6 5.93 5 282.7 0.6 0 //