ACCESSION: MSBNK-Athens_Univ-AU283405
RECORD_TITLE: Mometasone fuorate; LC-ESI-QTOF; MS2; CE: 50 eV; R=35000; [M+H]+
DATE: 2019.05.31
AUTHORS: Nikiforos Alygizakis, Katerina Galani, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2019 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 2834
CH$NAME: Mometasone fuorate
CH$NAME: Mometasone furoate
CH$NAME: [(8S,9R,10S,11S,13S,14S,16R,17R)-9-chloro-17-(2-chloroacetyl)-11-hydroxy-10,13,16-trimethyl-3-oxo-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-17-yl] furan-2-carboxylate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C27H30Cl2O6
CH$EXACT_MASS: 520.1419440
CH$SMILES: C[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@]4(C)[C@@]3(Cl)[C@@H](O)C[C@]2(C)[C@@]1(OC(=O)C1=CC=CO1)C(=O)CCl
CH$IUPAC: InChI=1S/C27H30Cl2O6/c1-15-11-19-18-7-6-16-12-17(30)8-9-24(16,2)26(18,29)21(31)13-25(19,3)27(15,22(32)14-28)35-23(33)20-5-4-10-34-20/h4-5,8-10,12,15,18-19,21,31H,6-7,11,13-14H2,1-3H3/t15-,18+,19+,21+,24+,25+,26+,27+/m1/s1
CH$LINK: CAS
83919-23-7
CH$LINK: CHEBI
47564
CH$LINK: KEGG
D00690
CH$LINK: PUBCHEM
CID:441336
CH$LINK: INCHIKEY
WOFMFGQZHJDGCX-ZULDAHANSA-N
CH$LINK: CHEMSPIDER
390091
CH$LINK: COMPTOX
DTXSID4023333
AC$INSTRUMENT: Bruker maXis Impact
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 50 eV
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo
AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min
AC$CHROMATOGRAPHY: RETENTION_TIME 10.632 min
AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate
MS$FOCUSED_ION: BASE_PEAK 467.1996
MS$FOCUSED_ION: PRECURSOR_M/Z 521.1492
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1
MS$DATA_PROCESSING: WHOLE RMassBank 2.10.1
PK$SPLASH: splash10-03ka-0590000000-91da285d72c72cd24d56
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
115.0539 C9H7+ 2 115.0542 -2.44
116.0584 C3H13ClO2+ 1 116.0599 -12.22
117.0692 C9H9+ 2 117.0699 -5.44
119.0848 C9H11+ 2 119.0855 -6.17
120.0549 C2H13ClO3+ 2 120.0548 1.16
121.0639 C8H9O+ 2 121.0648 -7.05
121.1006 C9H13+ 2 121.1012 -5.06
122.0668 C7[13]CH9O+ 1 122.0687 -15.87
128.0623 C10H8+ 2 128.0621 2.31
129.0679 C4H14ClO2+ 2 129.0677 2.03
130.0754 C4H15ClO2+ 2 130.0755 -1.01
131.025 C6H8ClO+ 2 131.0258 -6.13
131.0482 C9H7O+ 2 131.0491 -7.01
131.0843 C4H16ClO2+ 2 131.0833 7.18
132.0556 C3H13ClO3+ 2 132.0548 6.63
132.0899 C4H17ClO2+ 1 132.0912 -9.79
133.0405 C6H10ClO+ 2 133.0415 -7.43
133.0647 C9H9O+ 2 133.0648 -0.68
133.1007 C10H13+ 2 133.1012 -3.79
134.0697 C3H15ClO3+ 2 134.0704 -5.35
135.0797 C9H11O+ 2 135.0804 -5.67
136.0832 C8[13]CH11O+ 1 136.0843 -8.44
137.0959 C9H13O+ 2 137.0961 -1.7
141.069 C11H9+ 2 141.0699 -5.93
142.0771 C11H10+ 2 142.0777 -4.31
143.0261 C7H8ClO+ 2 143.0258 1.88
143.0616 C8H12Cl+ 2 143.0622 -4.46
143.0846 C11H11+ 2 143.0855 -6.81
144.0557 C4H13ClO3+ 2 144.0548 6.3
144.0905 C5H17ClO2+ 2 144.0912 -4.74
145.0634 C4H14ClO3+ 2 145.0626 5.74
145.1003 C11H13+ 2 145.1012 -5.81
146.0714 C4H15ClO3+ 2 146.0704 6.86
146.1047 C10[13]CH13+ 1 146.1051 -2.5
147.0794 C10H11O+ 2 147.0804 -6.81
148.0829 C9[13]CH11O+ 1 148.0843 -9.72
149.0945 C4H18ClO3+ 2 149.0939 3.72
151.0744 C9H11O2+ 2 151.0754 -6.03
152.0621 C12H8+ 2 152.0621 0.28
153.0471 C9H10Cl+ 2 153.0466 3.5
153.0693 Cl2H19O4+ 3 153.0655 24.73
154.0741 Cl2H20O4+ 3 154.0733 4.84
155.0597 H19Cl[37]ClO4+ 1 155.0631 -21.65
155.084 C6H16ClO2+ 3 155.0833 4.41
156.0556 C5H13ClO3+ 2 156.0548 5.19
156.0916 C6H17ClO2+ 3 156.0912 2.9
157.0403 C2H15Cl2O3+ 2 157.0393 6.67
157.0642 C11H9O+ 2 157.0648 -3.49
157.1002 C12H13+ 3 157.1012 -6.26
158.0715 C5H15ClO3+ 2 158.0704 6.8
158.1052 Cl2H24O4+ 3 158.1046 3.44
159.0793 C11H11O+ 2 159.0804 -7.29
159.115 C6H20ClO2+ 3 159.1146 2.51
160.0839 C10[13]CH11O+ 1 160.0843 -2.98
161.0587 C10H9O2+ 2 161.0597 -6.31
161.0946 C11H13O+ 2 161.0961 -9.51
162.0994 C10[13]CH13O+ 1 162.1 -3.44
163.0301 C10H8Cl+ 2 163.0309 -4.64
163.0738 C4H16ClO4+ 2 163.0732 3.91
163.1138 C11H15O+ 2 163.1117 12.66
165.0476 C10H10Cl+ 2 165.0466 6.54
165.0694 C13H9+ 3 165.0699 -2.64
166.0763 C7H15ClO2+ 3 166.0755 4.63
167.0608 C4H17Cl2O2+ 2 167.06 4.85
167.086 C13H11+ 2 167.0855 2.99
168.059 C12H8O+ 2 168.057 12.07
168.0913 C7H17ClO2+ 3 168.0912 1.09
169.0391 C3H15Cl2O3+ 2 169.0393 -0.84
169.064 C12H9O+ 3 169.0648 -4.75
169.1009 C13H13+ 3 169.1012 -1.91
170.0711 C6H15ClO3+ 3 170.0704 3.86
170.1069 C7H19ClO2+ 3 170.1068 0.5
171.0555 C3H17Cl2O3+ 2 171.0549 3.55
171.0795 C12H11O+ 3 171.0804 -5.28
171.1152 C7H20ClO2+ 3 171.1146 3.54
172.0851 C11[13]CH11O+ 1 172.0843 4.12
172.1192 CH26Cl2O4+ 2 172.1203 -6.26
173.0952 C12H13O+ 3 173.0961 -5.29
174.0991 C11[13]CH13O+ 1 174.1 -5.08
175.1111 C12H15O+ 3 175.1117 -3.95
177.0463 C11H10Cl+ 2 177.0466 -1.59
178.076 C8H15ClO2+ 3 178.0755 2.81
179.0624 C11H12Cl+ 2 179.0622 1.18
179.0841 C8H16ClO2+ 3 179.0833 4.52
180.09 C2H22Cl2O4+ 3 180.089 6.01
181.0423 C10H10ClO+ 2 181.0415 4.64
181.063 CH19Cl2O5+ 3 181.0604 14.57
181.1007 C14H13+ 3 181.1012 -2.36
182.0708 C7H15ClO3+ 3 182.0704 2.3
183.0547 CH19Cl[37]ClO5+ 1 183.058 -17.96
183.0795 CH21Cl2O5+ 3 183.0761 18.55
183.1174 C14H15+ 2 183.1168 3.24
184.0869 C7H17ClO3+ 3 184.0861 4.28
185.0716 CH21Cl[37]ClO5+ 1 185.0737 -10.93
185.0951 C13H13O+ 3 185.0961 -5.18
186.1004 C12[13]CH13O+ 1 186.1 2.07
187.0504 C3H17Cl2O4+ 3 187.0498 2.97
187.0748 C12H11O2+ 3 187.0754 -3.17
187.1104 C7H20ClO3+ 3 187.1095 4.36
188.0778 C11[13]CH11O2+ 1 188.0793 -7.87
188.1164 C7H21ClO3+ 3 188.1174 -5.19
189.0666 C3H19Cl2O4+ 3 189.0655 5.75
190.0751 C9H15ClO2+ 3 190.0755 -2.28
191.0605 C12H12Cl+ 2 191.0622 -8.98
191.0858 C3H21Cl2O4+ 3 191.0811 24.37
192.0634 C11[13]CH12Cl+ 1 192.0661 -13.92
192.0938 C15H12+ 2 192.0934 2.59
193.0416 C11H10ClO+ 2 193.0415 0.89
193.059 C12H12[37]Cl+ 1 193.0598 -3.97
193.0759 C3H21Cl[37]ClO4+ 1 193.0787 -14.55
193.1006 C15H13+ 3 193.1012 -3.16
194.0726 C14H10O+ 3 194.0726 -0.01
194.1071 C9H19ClO2+ 3 194.1068 1.32
195.0564 C11H12ClO+ 2 195.0571 -3.66
195.0784 C8H16ClO3+ 3 195.0782 0.79
195.1158 C15H15+ 3 195.1168 -5.12
196.0855 C8H17ClO3+ 3 196.0861 -2.98
196.1211 C3H26Cl2O4+ 3 196.1203 4.02
197.0564 C11H12[37]ClO+ 1 197.0547 8.51
197.0723 C8H16[37]ClO3+ 1 197.0758 -18.11
197.0955 C14H13O+ 3 197.0961 -2.93
198.1038 C14H14O+ 3 198.1039 -0.65
199.0737 C13H11O2+ 3 199.0754 -8.36
199.1106 C14H15O+ 3 199.1117 -5.57
200.0809 C12[13]CH11O2+ 1 200.0793 8.38
200.1109 C13[13]CH15O+ 1 200.1156 -23.7
203.0841 C4H21Cl2O4+ 3 203.0811 14.76
204.091 C10H17ClO2+ 3 204.0912 -0.92
205.0439 C12H10ClO+ 3 205.0415 11.76
205.0767 C4H21Cl[37]ClO4+ 1 205.0787 -10.11
205.1007 C16H13+ 3 205.1012 -2.48
206.0726 C15H10O+ 3 206.0726 0.04
206.1067 C10H19ClO2+ 3 206.1068 -0.46
207.0559 C12H12ClO+ 2 207.0571 -5.76
207.0801 C3H21Cl2O5+ 3 207.0761 19.45
207.1154 C16H15+ 3 207.1168 -6.67
208.0558 C14H8O2+ 1 208.0519 18.86
208.0874 C15H12O+ 3 208.0883 -3.98
208.1232 C15[13]CH15+ 1 208.1207 11.96
209.0551 C12H12[37]ClO+ 1 209.0547 1.74
209.0709 C3H21Cl[37]ClO5+ 1 209.0737 -13.33
209.095 C9H18ClO3+ 3 209.0939 5.11
209.1321 C16H17+ 3 209.1325 -1.8
210.102 C9H19ClO3+ 3 210.1017 1.22
211.0732 C8H16ClO4+ 3 211.0732 -0.02
211.1104 C9H20ClO3+ 3 211.1095 4.25
212.0837 C14H12O2+ 3 212.0832 2.57
212.1166 C9H21ClO3+ 3 212.1174 -3.79
213.0913 C14H13O2+ 3 213.091 1.5
213.1257 C9H22ClO3+ 3 213.1252 2.15
215.0849 C17H11+ 3 215.0855 -3.05
216.0664 C8H18Cl2O2+ 3 216.0678 -6.88
216.0917 C11H17ClO2+ 3 216.0912 2.4
217.0995 C11H18ClO2+ 3 217.099 2.48
218.0733 C16H10O+ 4 218.0726 3.12
218.1089 C17H14+ 3 218.109 -0.42
219.055 C7H17Cl2O3+ 2 219.0549 0.41
219.079 C10H16ClO3+ 3 219.0782 3.38
219.1158 C17H15+ 3 219.1168 -4.84
220.0879 C16H12O+ 3 220.0883 -1.55
220.1239 C17H16+ 3 220.1247 -3.5
221.0948 C10H18ClO3+ 3 221.0939 4.02
221.1319 C17H17+ 3 221.1325 -2.44
222.1027 C10H19ClO3+ 3 222.1017 4.43
223.1107 C16H15O+ 3 223.1117 -4.53
224.1178 C10H21ClO3+ 3 224.1174 1.87
225.1259 C16H17O+ 3 225.1274 -6.48
226.0998 C3H24Cl2O6+ 3 226.0944 23.68
226.132 C15[13]CH17O+ 1 226.1313 3.27
227.1056 C15H15O2+ 3 227.1067 -4.63
227.1394 C4H29Cl2O5+ 3 227.1387 3.1
228.0907 C3H24Cl[37]ClO6+ 1 228.092 -5.9
229.0421 C14H10ClO+ 3 229.0415 2.86
229.0801 C15H14Cl+ 3 229.0779 9.69
229.0997 C12H18ClO2+ 3 229.099 3.08
230.1078 C12H19ClO2+ 3 230.1068 4.41
231.0838 C10H15O6+ 3 231.0863 -10.94
231.1139 C12H20ClO2+ 3 231.1146 -3.06
232.0873 C17H12O+ 3 232.0883 -4.33
232.1231 C12H21ClO2+ 3 232.1225 2.88
233.0699 C8H19Cl2O3+ 2 233.0706 -2.75
233.0951 C17H13O+ 3 233.0961 -4.45
233.1318 C18H17+ 3 233.1325 -3.08
234.1026 C11H19ClO3+ 3 234.1017 3.68
235.0717 C8H19Cl[37]ClO3+ 1 235.0682 15.19
235.1105 C11H20ClO3+ 3 235.1095 3.86
235.1495 C18H19+ 4 235.1481 5.77
236.1172 C11H21ClO3+ 3 236.1174 -0.75
236.1502 C17[13]CH19+ 1 236.152 -7.84
237.1266 C17H17O+ 3 237.1274 -3.14
238.1309 C16[13]CH17O+ 1 238.1313 -1.83
239.1026 C4H25Cl2O6+ 3 239.1023 1.38
239.1428 C17H19O+ 3 239.143 -1.21
240.1463 C5H30Cl2O5+ 4 240.1465 -0.55
241.1207 C10H22ClO4+ 3 241.1201 2.32
242.1073 C13H19ClO2+ 3 242.1068 2.07
243.0571 C15H12ClO+ 3 243.0571 0.09
243.1147 C13H20ClO2+ 3 243.1146 0.28
244.0623 C9H18Cl2O3+ 2 244.0628 -1.78
244.0864 C12H17ClO3+ 3 244.0861 1.34
244.1257 C19H16+ 4 244.1247 4.31
245.0719 C9H19Cl2O3+ 2 245.0706 5.59
245.0957 C6H23Cl2O5+ 3 245.0917 16.13
245.1323 C19H17+ 4 245.1325 -0.76
246.1023 C12H19ClO3+ 3 246.1017 2.19
246.1373 C18[13]CH17+ 1 246.1364 3.71
247.0668 C9H19Cl[37]ClO3+ 1 247.0682 -5.65
247.0877 C6H23Cl[37]ClO5+ 1 247.0893 -6.55
247.1119 C18H15O+ 4 247.1117 0.48
247.147 C13H24ClO2+ 3 247.1459 4.11
248.1187 C18H16O+ 3 248.1196 -3.49
249.0906 C17H13O2+ 3 249.091 -1.5
249.1262 C12H22ClO3+ 3 249.1252 4
249.1622 C13H26ClO2+ 3 249.1616 2.51
250.097 C11H19ClO4+ 3 250.0966 1.56
250.1339 C12H23ClO3+ 3 250.133 3.51
250.1718 C19H22+ 3 250.1716 0.62
251.1085 C5H25Cl2O6+ 3 251.1023 24.63
251.1424 C18H19O+ 3 251.143 -2.74
251.1748 C13H28ClO2+ 2 251.1772 -9.88
252.1468 C6H30Cl2O5+ 4 252.1465 1.25
253.1011 C5H25Cl[37]ClO6+ 1 253.0999 4.74
253.1222 C17H17O2+ 3 253.1223 -0.57
253.1557 C12H26ClO3+ 3 253.1565 -3.32
255.1169 C20H15+ 4 255.1168 0.14
257.0715 C10H19Cl2O3+ 2 257.0706 3.55
257.0868 C7H23Cl2O5+ 3 257.0917 -19.11
257.0972 C7H23Cl2O5+ 4 257.0917 21.39
257.1325 C20H17+ 4 257.1325 -0.01
258.0786 C10H20Cl2O3+ 2 258.0784 0.75
258.1031 C19H14O+ 3 258.1039 -3.27
258.1391 C14H23ClO2+ 3 258.1381 3.67
259.1109 C19H15O+ 3 259.1117 -3.16
259.1476 C20H19+ 4 259.1481 -2.07
260.1195 C19H16O+ 4 260.1196 -0.34
260.1539 C14H25ClO2+ 3 260.1538 0.73
261.0678 C15H14ClO2+ 3 261.0677 0.53
261.1263 C13H22ClO3+ 3 261.1252 4.13
261.1629 C20H21+ 3 261.1638 -3.18
262.0962 C12H19ClO4+ 3 262.0966 -1.55
262.1343 C19H18O+ 3 262.1352 -3.43
262.168 C19[13]CH21+ 1 262.1677 1.06
263.1426 C19H19O+ 4 263.143 -1.52
264.113 C12H21ClO4+ 3 264.1123 2.83
264.1463 C18[13]CH19O+ 1 264.1469 -2.33
265.1185 C6H27Cl2O6+ 4 265.1179 2.3
265.1523 C17[13]C2H19O+ 1 265.1503 7.47
266.162 C13H27ClO3+ 3 266.1643 -8.57
268.1246 C21H16+ 4 268.1247 -0.36
269.1276 C15H22ClO2+ 3 269.1303 -9.9
269.1366 C21H17+ 3 269.1325 15.28
270.1359 C9H28Cl2O4+ 3 270.1359 -0.16
271.0866 C11H21Cl2O3+ 2 271.0862 1.23
271.1124 C20H15O+ 4 271.1117 2.45
271.1488 C21H19+ 4 271.1481 2.4
272.1178 C14H21ClO3+ 3 272.1174 1.73
273.1265 C20H17O+ 4 273.1274 -3.35
273.1619 C21H21+ 3 273.1638 -6.85
274.1323 C14H23ClO3+ 3 274.133 -2.51
274.1686 C20[13]CH21+ 1 274.1677 3.48
275.1079 C19H15O2+ 3 275.1067 4.4
275.142 C20H19O+ 3 275.143 -3.88
276.1142 C19H16O2+ 3 276.1145 -1.08
276.1485 C14H25ClO3+ 3 276.1487 -0.76
277.1218 C19H17O2+ 3 277.1223 -1.9
277.158 C20H21O+ 4 277.1587 -2.44
278.1258 C7H28Cl2O6+ 4 278.1257 0.07
278.1659 C20H22O+ 3 278.1665 -2.13
279.1392 C19H19O2+ 3 279.138 4.36
279.1728 C14H28ClO3+ 2 279.1721 2.44
280.1767 C13[13]CH28ClO3+ 1 280.1761 2.48
281.0674 C12H19Cl2O3+ 2 281.0706 -11.41
281.1526 C7H31Cl2O6+ 3 281.1492 11.94
283.1475 C7H31Cl[37]ClO6+ 1 283.1468 2.39
285.128 C21H17O+ 4 285.1274 2.19
286.1347 C21H18O+ 4 286.1352 -1.72
287.142 C21H19O+ 4 287.143 -3.58
288.1506 C21H20O+ 4 288.1509 -0.91
289.1235 C20H17O2+ 3 289.1223 4.29
289.1546 C20[13]CH20O+ 1 289.1548 -0.45
290.1317 C20H18O2+ 3 290.1301 5.24
291.1375 C14H24ClO4+ 3 291.1358 5.97
291.1755 C15H28ClO3+ 3 291.1721 11.44
292.1401 C13[13]CH24ClO4+ 1 292.1397 1.57
292.1751 C14[13]CH28ClO3+ 1 292.1761 -3.4
295.0853 C19H16ClO+ 2 295.0884 -10.57
295.0939 C19H16ClO+ 3 295.0884 18.58
296.0956 C19H17ClO+ 3 296.0962 -2.31
296.1748 C14H29ClO4+ 2 296.1749 -0.34
297.1034 C19H18ClO+ 3 297.1041 -2.16
299.0812 C12H21Cl2O4+ 3 299.0811 0.29
299.1192 C19H20ClO+ 3 299.1197 -1.89
300.1241 C13H26Cl2O3+ 2 300.1254 -4.11
301.1185 C19H20[37]ClO+ 1 301.1173 3.79
301.1587 C22H21O+ 4 301.1587 -0.1
302.166 C22H22O+ 3 302.1665 -1.87
303.1731 C16H28ClO3+ 3 303.1721 3.09
304.1476 C21H20O2+ 3 304.1458 6.07
305.151 C15H26ClO4+ 3 305.1514 -1.31
306.1615 C15H27ClO4+ 2 306.1592 7.29
307.089 C20H16ClO+ 4 307.0884 1.94
307.1632 C14[13]CH27ClO4+ 1 307.1631 0.19
309.1025 C14H23Cl2O3+ 3 309.1019 2.02
310.0981 C22H14O2+ 3 310.0988 -2.2
311.1014 C14H23Cl[37]ClO3+ 1 311.0995 6.05
313.0984 C19H18ClO2+ 3 313.099 -1.99
314.141 C14H28Cl2O3+ 2 314.141 -0.08
315.1417 C22H19O2+ 3 315.138 11.75
319.1698 C22H23O2+ 2 319.1693 1.79
320.1725 C21[13]CH23O2+ 1 320.1732 -1.96
322.1159 C14H23ClO6+ 4 322.1178 -5.76
327.1497 C15H29Cl2O3+ 3 327.1488 2.53
337.1385 C22H22ClO+ 4 337.1354 9.2
339.1325 C22H22[37]ClO+ 1 339.133 -1.47
355.1437 C16H29Cl2O4+ 2 355.1437 -0.11
356.1477 C16H30Cl2O4+ 3 356.1516 -10.79
PK$NUM_PEAK: 316
PK$PEAK: m/z int. rel.int.
115.0539 1984 46
116.0584 536 12
117.0692 1236 28
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//
