ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP007265
RECORD_TITLE: METHYL (2R,3R,4S)-3-(TERT-BUTYLDIMETHYLSILYLOXY)-2,4-DIMETHYLHEXANOATE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: ITO S, DEPT. OF CHEM., TOHOKU UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: METHYL (2R,3R,4S)-3-(TERT-BUTYLDIMETHYLSILYLOXY)-2,4-DIMETHYLHEXANOATE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₅H₃₂O₃Si
CH$EXACT_MASS: 288.21207
CH$SMILES: COC(=O)C(C)C([H])(C([H])(C)CC)O[Si](C)(C)C(C)(C)C
CH$IUPAC: InChI=1S/C15H32O3Si/c1-10-11(2)13(12(3)14(16)17-7)18-19(8,9)15(4,5)6/h11-13H,10H2,1-9H3/t11-,12-,13-/m0/s1
CH$LINK: INCHIKEY KOCLWUYPTOWPJL-AVGNSLFASA-N

AC$INSTRUMENT: HITACHI M-52
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 14 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-001i-0090000000-382b50c27ddd14201c84
PK$NUM_PEAK: 11
PK$PEAK: m/z int. rel.int.
  43 2.6 26
  58 3.3 33
  69 2 20
  75 0.27 3
  97 3.7 37
  115 9.7 97
  125 2.1 21
  201 1.64 16
  202 2.3 23
  231 99.99 999
  232 14.5 145
//