ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP011383
RECORD_TITLE: 4-METHOXY-6-METHYL-3-(TRIMETHYLSILYL)METHYL-1-HEPTENE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: HISAHIRO HAGIWARA, INSTITUTE FOR CHEMICAL REACTION SCIENCE TOHOKU UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: 4-METHOXY-6-METHYL-3-(TRIMETHYLSILYL)METHYL-1-HEPTENE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₃H₂₈OSi
CH$EXACT_MASS: 228.19094
CH$SMILES: COC(CC(C)C)C(C=C)C[Si](C)(C)C
CH$IUPAC: InChI=1S/C13H28OSi/c1-8-12(10-15(5,6)7)13(14-4)9-11(2)3/h8,11-13H,1,9-10H2,2-7H3
CH$LINK: INCHIKEY NQDYFUFXDDHZLI-UHFFFAOYSA-N

AC$INSTRUMENT: JEOL JMS-DX-300
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0v4j-9200000000-c3825eecb7108ff72691
PK$NUM_PEAK: 37
PK$PEAK: m/z int. rel.int.
  31 2.5 25
  33 3 30
  39 3.4 34
  41 13.2 132
  42 1.2 12
  43 23.8 238
  44 3.4 34
  45 56.1 561
  46 1.9 19
  53 1.9 19
  54 1.2 12
  55 3.5 35
  57 1.7 17
  58 5.2 52
  59 49.1 491
  60 2.4 24
  67 9.4 94
  68 1.5 15
  69 68.8 688
  70 5.1 51
  71 13.6 136
  72 2 20
  73 49.3 493
  74 4.7 47
  75 4.2 42
  81 1.7 17
  82 1.2 12
  85 3.3 33
  89 31.3 313
  90 2.9 29
  91 1.5 15
  95 1.1 11
  97 3.3 33
  101 99.99 999
  102 8.6 86
  103 1.6 16
  127 1.3 13
//