ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP011957
RECORD_TITLE: CIS-1-METHOXY-4-TRIMETHYLSILYLBUT-1-EN-3-YNE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: ISHIKAWA M, HIROSHIMA UNIV. FAC. TEQUNOLOGY
LICENSE: CC BY-NC-SA

CH$NAME: CIS-1-METHOXY-4-TRIMETHYLSILYLBUT-1-EN-3-YNE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₈H₁₄OSi
CH$EXACT_MASS: 154.08139
CH$SMILES: COC=CC#C[Si](C)(C)C
CH$IUPAC: InChI=1S/C8H14OSi/c1-9-7-5-6-8-10(2,3)4/h5,7H,1-4H3/b7-5-
CH$LINK: INCHIKEY KHAWMPYFFORPIN-ALCCZGGFSA-N

AC$INSTRUMENT: SHIMADZU QP-1000
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0rki-9300000000-3d3b802fb07c7e5aade8
PK$NUM_PEAK: 51
PK$PEAK: m/z int. rel.int.
  52 5.3 53
  53 10 100
  54 64.2 642
  55 14.7 147
  56 43.2 432
  57 3.7 37
  58 8.9 89
  59 12.6 126
  60 93.2 932
  61 8.4 84
  62 21.1 211
  63 2.1 21
  64 9.5 95
  65 39.5 395
  66 18.4 184
  67 31.6 316
  68 5.3 53
  69 25.3 253
  70 17.9 179
  71 11.6 116
  72 2.1 21
  73 7.4 74
  75 10 100
  77 15.3 153
  78 3.2 32
  79 9.5 95
  80 2.1 21
  81 6.3 63
  83 43.2 432
  84 4.2 42
  85 17.4 174
  87 2.1 21
  89 3.2 32
  93 3.2 32
  94 1.1 11
  95 7.4 74
  97 3.2 32
  98 1.1 11
  99 3.2 32
  107 2.1 21
  109 56.8 568
  110 6.3 63
  111 8.9 89
  113 3.2 32
  123 2.1 21
  124 3.2 32
  139 99.99 999
  140 12.1 121
  141 3.2 32
  154 22.1 221
  155 2.1 21
//