ACCESSION: MSBNK-Osaka_Univ-OUF00210
RECORD_TITLE: D-(-)-Ribose; GC-EI-TOF; MS; n TMS; RT:628.632 sec
DATE: 2016.01.19 (Created 2010.05.20, modified 2013.04.24)
AUTHORS: Tsujimoto Y, Tsugawa H, Bamba T, Fukusaki E, engineering department, Osaka Univ.
LICENSE: CC BY-SA
COMMENT: The chemical compound was chemically modified with N-methyl-N-trimethylsilyl-trifluoroacetamide (MSTFA) before GC-MS analysis. When it has two or more functional groups, this modification gave a mixture of the TMS derivatives having different number of TMS groups at different functional groups.

CH$NAME: D-(-)-Ribose
CH$COMPOUND_CLASS: Natural Product
CH$FORMULA: C₅H₁₀O₅
CH$EXACT_MASS: 150.05282
CH$SMILES: OC[C@@H](O1)[C@@H](O)[C@@H](O)C(O)1
CH$IUPAC: InChI=1S/C5H10O5/c6-1-2-3(7)4(8)5(9)10-2/h2-9H,1H2/t2-,3-,4-,5?/m1/s1
CH$LINK: CAS 50-69-1
CH$LINK: CHEBI 130464
CH$LINK: CHEMSPIDER 968
CH$LINK: PUBCHEM 993
CH$LINK: INCHIKEY HMFHBZSHGGEWLO-SOOFDHNKSA-N

AC$INSTRUMENT: Pegasus III TOF-MS system, Leco; GC 6890, Agilent Technologies
AC$INSTRUMENT_TYPE: GC-EI-TOF
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: HELIUM_FLOW 1 ml/min
AC$MASS_SPECTROMETRY: ION_SOURCE_TEMPERATURE 200 C
AC$MASS_SPECTROMETRY: SCAN_RANGE_M/Z 85-500
AC$CHROMATOGRAPHY: COLUMN_NAME CP-SIL 8 CB LOW BLEED/MS
AC$CHROMATOGRAPHY: INJECTION_TEMPERATURE 230 C
AC$CHROMATOGRAPHY: OVEN_TEMPERATURE 80 C (Duration 2 min)-330 C (rate: 15 C/min; Duration 6 min)
AC$CHROMATOGRAPHY: RETENTION_INDEX 1659.062
AC$CHROMATOGRAPHY: RETENTION_TIME 628.632 sec
AC$CHROMATOGRAPHY: TRANSFARLINE_TEMPERATURE 250 C

MS$DATA_PROCESSING: WHOLE ChromaTOF ver. 2.32 (LECO)

PK$SPLASH: splash10-0uxr-0920000000-d29b5079ba0fde220b0d
PK$NUM_PEAK: 156
PK$PEAK: m/z int. rel.int.
  85 10 10
  86 13 13
  87 15 15
  88 10 10
  89 131 131
  90 11 11
  91 6 6
  92 1 1
  94 2 2
  95 1 1
  96 1 1
  97 1 1
  98 5 5
  99 11 11
  100 42 42
  101 47 47
  102 23 23
  103 999 999
  104 98 98
  105 69 69
  106 5 5
  107 2 2
  110 1 1
  111 4 4
  112 5 5
  113 11 11
  114 23 23
  115 19 19
  116 15 15
  117 106 106
  118 12 12
  119 18 18
  120 2 2
  121 1 1
  126 6 6
  127 7 7
  128 8 8
  129 92 92
  130 22 22
  131 49 49
  132 10 10
  133 125 125
  134 18 18
  135 11 11
  136 1 1
  140 3 3
  141 3 3
  142 9 9
  143 21 21
  144 4 4
  145 16 16
  146 3 3
  147 347 347
  148 57 57
  149 38 38
  150 5 5
  151 3 3
  152 1 1
  154 1 1
  155 1 1
  156 2 2
  157 7 7
  158 12 12
  159 5 5
  160 82 82
  161 21 21
  162 5 5
  163 16 16
  164 3 3
  165 1 1
  168 7 7
  169 3 3
  170 2 2
  172 5 5
  173 8 8
  174 14 14
  175 12 12
  176 3 3
  177 4 4
  178 1 1
  184 1 1
  186 1 1
  187 1 1
  188 1 1
  189 128 128
  190 27 27
  191 37 37
  192 7 7
  193 3 3
  198 5 5
  199 1 1
  200 4 4
  201 10 10
  202 3 3
  203 6 6
  204 34 34
  205 39 39
  206 9 9
  207 7 7
  208 1 1
  214 1 1
  215 3 3
  216 11 11
  217 402 402
  218 87 87
  219 40 40
  220 6 6
  221 10 10
  222 2 2
  223 1 1
  228 2 2
  229 1 1
  230 2 2
  231 8 8
  232 5 5
  233 30 30
  234 10 10
  235 4 4
  240 2 2
  242 4 4
  243 2 2
  244 1 1
  246 2 2
  248 3 3
  256 3 3
  257 3 3
  258 1 1
  262 11 11
  263 3 3
  264 1 1
  272 2 2
  274 5 5
  275 1 1
  276 1 1
  277 30 30
  278 13 13
  279 6 6
  280 2 2
  288 2 2
  290 1 1
  291 4 4
  292 1 1
  305 2 2
  306 3 3
  307 142 142
  308 45 45
  309 21 21
  310 4 4
  311 1 1
  319 1 1
  330 1 1
  331 1 1
  332 1 1
  362 2 2
  467 1 1
  468 1 1
//