ACCESSION: MSBNK-Eawag-EQ366707
RECORD_TITLE: Enrofloxacin; LC-ESI-QFT; MS2; CE: 120; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs M, Schymanski E, Singer H, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3667
CH$NAME: Enrofloxacin
CH$NAME: 1-cyclopropyl-7-(4-ethylpiperazin-4-ium-1-yl)-6-fluoro-4-oxoquinoline-3-carboxylate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C19H22FN3O3
CH$EXACT_MASS: 359.16452
CH$SMILES: CCN1CCN(CC1)C2=C(C=C3C(=C2)N(C=C(C3=O)C(=O)O)C4CC4)F
CH$IUPAC: InChI=1S/C19H22FN3O3/c1-2-21-5-7-22(8-6-21)17-10-16-13(9-15(17)20)18(24)14(19(25)26)11-23(16)12-3-4-12/h9-12H,2-8H2,1H3,(H,25,26)
CH$LINK: CAS
93106-60-6
CH$LINK: CHEBI
35720
CH$LINK: PUBCHEM
CID:71188
CH$LINK: INCHIKEY
SPFYMRJSYKOXGV-UHFFFAOYSA-N
CH$LINK: CHEMSPIDER
64326
CH$LINK: COMPTOX
DTXSID1045619
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 120 (nominal)
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min
AC$CHROMATOGRAPHY: RETENTION_TIME 4.4 min
AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 360.1712
MS$FOCUSED_ION: PRECURSOR_M/Z 360.1718
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-0ka2-1900000000-253c46c9c07205bffb6f
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
50.0151 C4H2+ 1 50.0151 -0.23
51.0229 C4H3+ 1 51.0229 -0.91
52.0181 C3H2N+ 1 52.0182 -0.49
53.0023 C3HO+ 1 53.0022 1.3
53.0386 C4H5+ 1 53.0386 0.44
53.9974 C2NO+ 1 53.9974 -0.19
54.0339 C3H4N+ 1 54.0338 1.56
55.0179 C3H3O+ 1 55.0178 0.34
55.0542 C4H7+ 1 55.0542 0.06
56.0495 C3H6N+ 1 56.0495 0.79
57.0136 C3H2F+ 1 57.0135 0.79
57.0574 C3H7N+ 1 57.0573 1.04
58.0652 C3H8N+ 1 58.0651 0.76
62.0151 C5H2+ 2 62.0151 -0.02
63.0229 C5H3+ 2 63.0229 0.21
65.0386 C5H5+ 2 65.0386 0.21
67.0416 C4H5N+ 1 67.0417 -0.46
67.0543 C5H7+ 2 67.0542 1.84
68.0495 C4H6N+ 1 68.0495 0.21
69.0447 C3H5N2+ 1 69.0447 -0.5
70.0652 C4H8N+ 1 70.0651 0.63
72.0808 C4H10N+ 1 72.0808 0.2
74.015 C6H2+ 2 74.0151 -0.83
75.0229 C6H3+ 2 75.0229 0.05
76.0307 C6H4+ 2 76.0308 -0.94
77.0022 C5HO+ 2 77.0022 0.38
77.0386 C6H5+ 2 77.0386 0.04
78.0337 C5H4N+ 1 78.0338 -1.1
78.0464 C6H6+ 2 78.0464 -0.41
80.0495 C5H6N+ 1 80.0495 0.55
81.0135 C5H2F+ 1 81.0135 -0.55
81.0336 C5H5O+ 2 81.0335 1.84
82.0652 C5H8N+ 1 82.0651 0.42
83.0292 C5H4F+ 1 83.0292 0.67
83.0603 C4H7N2+ 1 83.0604 -0.54
84.037 C5H5F+ 1 84.037 0.24
84.0809 C5H10N+ 1 84.0808 1.12
86.0964 C5H12N+ 1 86.0964 -0.18
87.0103 C6HN+ 1 87.0104 -0.58
87.0229 C7H3+ 2 87.0229 0.15
88.0183 C6H2N+ 1 88.0182 1.3
88.0308 C7H4+ 2 88.0308 1
89.0386 C7H5+ 2 89.0386 0.6
90.0339 C6H4N+ 1 90.0338 0.94
90.0465 C7H6+ 2 90.0464 0.98
91.0417 C6H5N+ 1 91.0417 0.54
91.0543 C7H7+ 2 91.0542 1.14
92.0257 C6H4O+ 2 92.0257 0.37
92.0495 C6H6N+ 1 92.0495 0.16
93.0137 C6H2F+ 1 93.0135 1.99
93.0337 C6H5O+ 2 93.0335 2.67
94.0216 C6H3F+ 1 94.0213 2.45
95.0292 C6H4F+ 1 95.0292 0.06
95.0492 C6H7O+ 2 95.0491 0.72
96.0371 C6H5F+ 1 96.037 1.56
96.0445 C5H6NO+ 1 96.0444 1.35
97.0324 C5H4FN+ 1 97.0322 1.56
97.0449 C6H6F+ 1 97.0448 0.57
97.0763 C5H9N2+ 1 97.076 2.42
98.084 C5H10N2+ 1 98.0838 1.02
99.023 C8H3+ 2 99.0229 0.34
100.0183 C7H2N+ 1 100.0182 0.85
101.0387 C8H5+ 2 101.0386 1.12
102.0339 C7H4N+ 1 102.0338 1.12
102.0465 C8H6+ 2 102.0464 1.16
103.0416 C7H5N+ 1 103.0417 -0.39
103.0543 C8H7+ 2 103.0542 0.91
104.0495 C7H6N+ 1 104.0495 0.43
105.0449 C6H5N2+ 1 105.0447 1.29
105.0573 C7H7N+ 1 105.0573 0.28
106.0214 C7H3F+ 1 106.0213 0.57
107.0292 C7H4F+ 1 107.0292 0.7
108.0245 C6H3FN+ 1 108.0244 0.71
108.037 C7H5F+ 1 108.037 0.65
109.0449 C7H6F+ 1 109.0448 0.96
110.0401 C6H5FN+ 1 110.0401 0.42
112.0185 C8H2N+ 1 112.0182 3.25
113.026 C8H3N+ 1 113.026 0.35
113.0389 C9H5+ 2 113.0386 2.68
114.034 C8H4N+ 1 114.0338 1.53
114.0466 C9H6+ 2 114.0464 1.48
115.0417 C8H5N+ 1 115.0417 0.17
115.0543 C9H7+ 2 115.0542 0.9
116.0496 C8H6N+ 1 116.0495 0.9
117.0574 C8H7N+ 1 117.0573 1.02
118.0287 C7H4NO+ 1 118.0287 -0.26
118.0651 C8H8N+ 1 118.0651 -0.13
119.0292 C8H4F+ 1 119.0292 -0.04
119.0492 C8H7O+ 2 119.0491 0.75
120.0245 C7H3FN+ 1 120.0244 1.05
120.0371 C8H5F+ 1 120.037 1
120.0442 C7H6NO+ 1 120.0444 -1.92
121.0323 C7H4FN+ 1 121.0322 0.84
121.0448 C8H6F+ 1 121.0448 -0.21
122.0402 C7H5FN+ 1 122.0401 0.95
123.0354 C6H4FN2+ 1 123.0353 0.87
123.048 C7H6FN+ 1 123.0479 0.66
124.0557 C7H7FN+ 1 124.0557 -0.27
125.0388 C10H5+ 2 125.0386 1.87
126.034 C9H4N+ 1 126.0338 1.15
126.0466 C10H6+ 2 126.0464 1.97
127.0419 C9H5N+ 1 127.0417 2.36
127.0543 C10H7+ 2 127.0542 0.66
128.0496 C9H6N+ 1 128.0495 0.97
128.0621 C10H8+ 2 128.0621 0.46
129.0448 C8H5N2+ 1 129.0447 0.89
129.0574 C9H7N+ 1 129.0573 0.54
129.0699 C10H9+ 2 129.0699 0.18
130.0403 C7H4N3+ 1 130.04 2.59
130.0653 C9H8N+ 1 130.0651 1.65
131.0292 C9H4F+ 1 131.0292 0.27
131.037 C8H5NO+ 1 131.0366 3.09
131.0606 C8H7N2+ 1 131.0604 1.64
132.0245 C8H3FN+ 1 132.0244 0.88
132.0368 C9H5F+ 1 132.037 -1.29
132.0445 C8H6NO+ 1 132.0444 0.91
133.0324 C8H4FN+ 1 133.0322 1.59
133.0449 C9H6F+ 1 133.0448 0.72
134.0402 C8H5FN+ 1 134.0401 0.94
134.0601 C8H8NO+ 1 134.06 0.67
135.0479 C8H6FN+ 1 135.0479 0.53
136.0195 C7H3FNO+ 1 136.0193 1.34
136.0559 C8H7FN+ 1 136.0557 1.37
137.0272 C7H4FNO+ 1 137.0271 0.19
137.0513 C7H6FN2+ 1 137.051 2.53
138.0349 C7H5FNO+ 1 138.035 -0.28
139.0294 C9H3N2+ 1 139.0291 2.27
139.0543 C11H7+ 2 139.0542 0.6
140.0372 C9H4N2+ 1 140.0369 2.29
140.0496 C10H6N+ 1 140.0495 1.1
141.0449 C9H5N2+ 1 141.0447 1.1
141.0574 C10H7N+ 1 141.0573 0.78
142.0289 C9H4NO+ 1 142.0287 1.2
142.0528 C9H6N2+ 1 142.0525 1.69
142.0653 C10H8N+ 1 142.0651 1.02
143.0493 C10H7O+ 2 143.0491 0.9
143.0605 C9H7N2+ 1 143.0604 0.95
143.0732 C10H9N+ 1 143.073 1.46
144.0244 C9H3FN+ 1 144.0244 0.18
144.0445 C9H6NO+ 1 144.0444 0.97
144.0558 C8H6N3+ 1 144.0556 1.02
144.0812 C10H10N+ 2 144.0808 3.22
145.0323 C9H4FN+ 1 145.0322 0.77
145.045 C10H6F+ 1 145.0448 1.14
145.065 C10H9O+ 2 145.0648 1.09
146.0402 C9H5FN+ 1 146.0401 1.07
146.0528 C10H7F+ 1 146.0526 0.89
146.0601 C9H8NO+ 1 146.06 0.41
147.0354 C8H4FN2+ 1 147.0353 0.53
147.048 C9H6FN+ 1 147.0479 1.03
147.0605 C10H8F+ 1 147.0605 0.31
148.0436 C8H5FN2+ 1 148.0431 3.46
148.0558 C9H7FN+ 1 148.0557 0.72
149.0513 C8H6FN2+ 1 149.051 1.99
149.0637 C9H8FN+ 1 149.0635 1.48
150.0352 C8H5FNO+ 1 150.035 1.34
150.0589 C8H7FN2+ 1 150.0588 0.61
150.0718 C9H9FN+ 1 150.0714 2.97
151.043 C8H6FNO+ 1 151.0428 1.7
151.0671 C8H8FN2+ 1 151.0666 3.09
152.0506 C8H7FNO+ 1 152.0506 -0.06
152.0621 C12H8+ 2 152.0621 0.12
153.0451 C10H5N2+ 2 153.0447 2.58
153.0573 C11H7N+ 1 153.0573 0.06
154.0402 C9H4N3+ 1 154.04 1.41
154.0653 C11H8N+ 1 154.0651 1.07
155.0605 C10H7N2+ 1 155.0604 0.94
155.073 C11H9N+ 1 155.073 0.32
156.0446 C10H6NO+ 1 156.0444 1.47
156.0683 C10H8N2+ 1 156.0682 0.58
156.0809 C11H10N+ 1 156.0808 0.92
157.0397 C9H5N2O+ 1 157.0396 0.64
157.0454 C11H6F+ 1 157.0448 3.98
157.0525 C10H7NO+ 1 157.0522 1.62
157.0762 C10H9N2+ 1 157.076 1.18
158.0403 C10H5FN+ 1 158.0401 1.75
158.0603 C10H8NO+ 1 158.06 1.39
159.036 C9H4FN2+ 1 159.0353 4.57
159.0481 C10H6FN+ 1 159.0479 1.2
159.0554 C9H7N2O+ 1 159.0553 0.82
160.0434 C9H5FN2+ 1 160.0431 1.89
160.0558 C10H7FN+ 1 160.0557 0.73
161.0273 C9H4FNO+ 1 161.0271 0.91
161.0513 C9H6FN2+ 1 161.051 2.03
161.0636 C10H8FN+ 1 161.0635 0.69
162.0352 C9H5FNO+ 1 162.035 1.31
162.0461 C8H5FN3+ 2 162.0462 -0.75
162.0587 C9H7FN2+ 1 162.0588 -0.6
162.0714 C10H9FN+ 1 162.0714 0.35
163.0428 C9H6FNO+ 1 163.0428 0.35
163.0553 C10H8FO+ 1 163.0554 -0.24
163.0667 C9H8FN2+ 1 163.0666 0.47
164.0507 C9H7FNO+ 1 164.0506 0.44
165.0451 C11H5N2+ 2 165.0447 2.27
166.0528 C11H6N2+ 1 166.0525 1.45
166.0655 C12H8N+ 2 166.0651 2.19
167.0607 C11H7N2+ 1 167.0604 1.65
167.0729 C12H9N+ 1 167.073 -0.06
168.0083 C10H2NO2+ 2 168.008 1.88
168.0446 C11H6NO+ 1 168.0444 1.37
168.0558 C10H6N3+ 1 168.0556 1.17
168.0683 C11H8N2+ 1 168.0682 0.72
168.0808 C12H10N+ 1 168.0808 0.08
169.0399 C10H5N2O+ 1 169.0396 1.6
169.0515 C11H7NO+ 1 169.0522 -4.17
169.0761 C11H9N2+ 1 169.076 0.68
170.0344 C9H4N3O+ 1 170.0349 -2.64
170.0472 C10H6N2O+ 1 170.0475 -1.61
170.0601 C11H8NO+ 1 170.06 0.12
171.0477 C11H6FN+ 1 171.0479 -0.87
171.0553 C10H7N2O+ 1 171.0553 0.12
172.0558 C11H7FN+ 1 172.0557 0.79
173.0513 C10H6FN2+ 1 173.051 2.24
173.0637 C11H8FN+ 1 173.0635 0.82
173.071 C10H9N2O+ 1 173.0709 0.06
174.0352 C10H5FNO+ 1 174.035 1.16
174.0591 C10H7FN2+ 1 174.0588 1.97
174.0713 C11H9FN+ 1 174.0714 -0.14
175.0429 C10H6FNO+ 1 175.0428 0.84
175.0668 C10H8FN2+ 1 175.0666 1.24
176.0509 C10H7FNO+ 1 176.0506 1.37
176.0747 C10H9FN2+ 1 176.0744 1.37
177.0464 C9H6FN2O+ 1 177.0459 2.78
177.0585 C10H8FNO+ 1 177.0584 0.26
178.0304 C9H5FNO2+ 1 178.0299 3.13
178.0659 C10H9FNO+ 2 178.0663 -2.24
179.0379 C9H6FNO2+ 1 179.0377 1.02
179.0607 C9H8FN2O+ 2 179.0615 -4.84
180.0457 C9H7FNO2+ 1 180.0455 1.2
180.0554 C11H6N3+ 1 180.0556 -1.52
180.0684 C12H8N2+ 1 180.0682 1.06
181.0761 C12H9N2+ 1 181.076 0.53
182.0603 C12H8NO+ 2 182.06 1.32
182.0842 C12H10N2+ 2 182.0838 1.98
183.0554 C11H7N2O+ 1 183.0553 0.39
183.0682 C12H9NO+ 2 183.0679 1.77
183.0922 C12H11N2+ 2 183.0917 2.65
184.0558 C12H7FN+ 1 184.0557 0.3
184.0635 C11H8N2O+ 2 184.0631 1.88
185.0516 C11H6FN2+ 1 185.051 3.39
185.0637 C12H8FN+ 1 185.0635 0.98
185.0714 C11H9N2O+ 2 185.0709 2.33
186.0589 C11H7FN2+ 1 186.0588 0.66
186.0714 C12H9FN+ 1 186.0714 0.36
187.0304 C10H4FN2O+ 1 187.0302 1.08
187.0429 C11H6FNO+ 1 187.0428 0.52
187.0668 C11H8FN2+ 1 187.0666 1.27
188.0145 C10H3FNO2+ 1 188.0142 1.37
188.0257 C9H3FN3O+ 2 188.0255 0.98
188.0383 C10H5FN2O+ 1 188.038 1.42
188.0508 C11H7FNO+ 1 188.0506 0.86
188.0745 C11H9FN2+ 1 188.0744 0.22
189.0461 C10H6FN2O+ 1 189.0459 1.12
189.0825 C11H10FN2+ 1 189.0823 1.31
190.0412 C14H6O+ 2 190.0413 -0.35
190.0665 C11H9FNO+ 1 190.0663 1.06
191.0614 C10H8FN2O+ 1 191.0615 -0.56
193.0762 C13H9N2+ 2 193.076 1.17
194.0613 C10H9FNO2+ 1 194.0612 0.4
195.0192 C11H3N2O2+ 2 195.0189 1.72
195.0556 C12H7N2O+ 2 195.0553 1.54
195.092 C13H11N2+ 2 195.0917 1.87
197.0711 C12H9N2O+ 2 197.0709 0.92
199.0668 C12H8FN2+ 1 199.0666 0.94
200.0507 C12H7FNO+ 1 200.0506 0.31
200.0747 C12H9FN2+ 1 200.0744 1.16
201.046 C11H6FN2O+ 1 201.0459 0.71
201.0588 C12H8FNO+ 1 201.0584 1.62
201.0823 C12H10FN2+ 1 201.0823 0.28
202.0306 C11H5FNO2+ 1 202.0299 3.65
202.0665 C12H9FNO+ 1 202.0663 0.95
202.0903 C12H11FN2+ 1 202.0901 1.3
203.0617 C11H8FN2O+ 1 203.0615 0.7
205.0767 C11H10FN2O+ 2 205.0772 -2.33
206.0252 C10H5FNO3+ 1 206.0248 2.1
208.0871 C13H10N3+ 2 208.0869 0.99
209.0713 C13H9N2O+ 2 209.0709 1.92
211.0667 C13H8FN2+ 1 211.0666 0.37
215.0253 C11H4FN2O2+ 1 215.0251 0.73
215.0616 C12H8FN2O+ 1 215.0615 0.2
217.0412 C11H6FN2O2+ 1 217.0408 1.97
227.0622 C13H8FN2O+ 1 227.0615 2.87
229.0775 C13H10FN2O+ 1 229.0772 1.49
233.0362 C11H6FN2O3+ 1 233.0357 2.07
243.0568 C13H8FN2O2+ 1 243.0564 1.64
PK$NUM_PEAK: 288
PK$PEAK: m/z int. rel.int.
50.0151 166162 16
51.0229 313331.5 30
52.0181 94360.4 9
53.0023 3972577.5 384
53.0386 296040.3 28
53.9974 89142.1 8
54.0339 66051.5 6
55.0179 93597.8 9
55.0542 187478.9 18
56.0495 3599579.5 348
57.0136 335523.4 32
57.0574 557963.6 53
58.0652 1410916.8 136
62.0151 86549.3 8
63.0229 689340.2 66
65.0386 463511.1 44
67.0416 168685.1 16
67.0543 52434.3 5
68.0495 609389.8 58
69.0447 67308.1 6
70.0652 3750059.2 362
72.0808 1063058.4 102
74.015 80712.8 7
75.0229 935301.2 90
76.0307 45567.5 4
77.0022 57308.3 5
77.0386 436734.3 42
78.0337 174941.5 16
78.0464 214716.8 20
80.0495 274375.9 26
81.0135 94606.7 9
81.0336 55415.2 5
82.0652 289182.7 27
83.0292 1757190 169
83.0603 194976.6 18
84.037 263937.3 25
84.0809 1155762 111
86.0964 342051 33
87.0103 44758.1 4
87.0229 235276 22
88.0183 57886.4 5
88.0308 292329.2 28
89.0386 4656424.5 450
90.0339 291699.1 28
90.0465 365735.9 35
91.0417 46043 4
91.0543 379826.9 36
92.0257 91369.2 8
92.0495 180465.9 17
93.0137 60402.7 5
93.0337 41833.4 4
94.0216 151375.2 14
95.0292 186088.2 17
95.0492 691741.2 66
96.0371 414042.8 40
96.0445 338192.6 32
97.0324 65535.9 6
97.0449 86830.9 8
97.0763 49326.3 4
98.084 98696.2 9
99.023 161956.6 15
100.0183 229135.6 22
101.0387 474673.1 45
102.0339 191333.3 18
102.0465 1002051.5 96
103.0416 157765.2 15
103.0543 771793.9 74
104.0495 613385.9 59
105.0449 638447.5 61
105.0573 219103.7 21
106.0214 292292.2 28
107.0292 5437431 525
108.0245 1038622.9 100
108.037 1567320.9 151
109.0449 2773084.2 268
110.0401 252808.8 24
112.0185 39789.8 3
113.026 72706.2 7
113.0389 378599.2 36
114.034 1531696.6 148
114.0466 197595.6 19
115.0417 983384.4 95
115.0543 2500578.8 241
116.0496 2094812.6 202
117.0574 986157.9 95
118.0287 229096.1 22
118.0651 190962.3 18
119.0292 67642.4 6
119.0492 391285.6 37
120.0245 164174.4 15
120.0371 1113921.6 107
120.0442 72536.3 7
121.0323 1211739.5 117
121.0448 486248.2 47
122.0402 1115564.4 107
123.0354 567111.4 54
123.048 162453.5 15
124.0557 154278.8 14
125.0388 307247.8 29
126.034 640629.2 61
126.0466 338087.6 32
127.0419 462295.2 44
127.0543 830870.4 80
128.0496 3146184.5 304
128.0621 1255816 121
129.0448 2122850.2 205
129.0574 1571233 151
129.0699 156418.2 15
130.0403 172506.5 16
130.0653 1298298.9 125
131.0292 91637.4 8
131.037 87445.4 8
131.0606 381908 36
132.0245 1825158.9 176
132.0368 177184 17
132.0445 505813.3 48
133.0324 1123308.5 108
133.0449 2184792 211
134.0402 6431965 621
134.0601 1086408.9 105
135.0479 5023012 485
136.0195 437895.9 42
136.0559 1085134.5 104
137.0272 44587.3 4
137.0513 51232.6 4
138.0349 167106.6 16
139.0294 286913.7 27
139.0543 183924.5 17
140.027 162364.3281 15
140.0372 149698.3 14
140.0496 1724146.4 166
141.0449 477600.4 46
141.0574 970520.6 93
142.0289 286503.1 27
142.0528 242234 23
142.0653 685287.3 66
143.0493 44527.4 4
143.0605 532341.9 51
143.0732 158696 15
144.0244 61914 5
144.0445 293624.2 28
144.0558 508541.7 49
144.0812 45689.3 4
145.0323 211789.9 20
145.045 82808.3 8
145.065 575288.4 55
146.0402 2046403.1 197
146.0528 1755354.2 169
146.0601 389751.4 37
147.0354 513157 49
147.048 1806706.4 174
147.0605 593514.1 57
148.0436 668541.6 64
148.0558 10332772 999
149.0513 534727.4 51
149.0637 244113.6 23
150.0352 414729.4 40
150.0589 296164.1 28
150.0718 68036.2 6
151.043 386700.3 37
151.0671 55360.8 5
152.0506 1204633.9 116
152.0621 155895.2 15
153.0451 316784.4 30
153.0573 364295.5 35
154.0402 898468.9 86
154.0653 4594800 444
155.0605 4716196.5 455
155.073 275839.8 26
156.0446 380496.8 36
156.0683 1532246.5 148
156.0809 173037.9 16
157.0397 190466.4 18
157.0454 75168.4 7
157.0525 83216.2 8
157.0762 271193 26
158.0403 1093714.6 105
158.0603 228307.2 22
159.036 64320.5 6
159.0481 1064562.6 102
159.0554 271324.8 26
160.0194 223961.4063 21
160.0434 638269.2 61
160.0558 917884.7 88
161.0273 611391.7 59
161.0513 3799752.8 367
161.0636 799480 77
162.0352 1791989.8 173
162.0461 948479.4 91
162.0587 550531.3 53
162.0714 355399.2 34
163.0428 318871.9 30
163.0553 58717.9 5
163.0667 256129.7 24
164.0507 766644.3 74
165.0451 89119.7 8
166.0528 416576.2 40
166.0655 285537.4 27
167.0607 901929.8 87
167.0729 378718.9 36
168.0083 91678.9 8
168.0446 89216.9 8
168.0558 184487.2 17
168.0683 903700.2 87
168.0808 228685.3 22
169.0399 72832 7
169.0515 81028.3 7
169.0761 629769.1 60
170.0344 50752.3 4
170.0472 41688.2 4
170.0601 217373 21
171.0477 72743.6 7
171.0553 73409.8 7
172.0558 3922442.8 379
173.0513 1777674.1 171
173.0637 1147625.9 110
173.071 143232.4 13
174.0352 2022890.9 195
174.0591 2605134.5 251
174.0713 1809288 174
175.0429 156457 15
175.0668 2314156.2 223
176.0509 983588.9 95
176.0747 1172031.9 113
177.0464 62369.3 6
177.0585 172414.9 16
178.0304 70360.6 6
178.0659 159057.4 15
179.0379 268579.7 25
179.0607 349317.2 33
180.0457 1604545.6 155
180.0554 164726 15
180.0684 207393.8 20
181.0761 1025566.5 99
182.0603 337280.5 32
182.0842 178095.9 17
183.0554 150086.9 14
183.0682 48560.3 4
183.0922 49942.2 4
184.0558 306330.8 29
184.0635 220068.8 21
185.0516 375877.2 36
185.0637 829411.4 80
185.0714 311377.4 30
186.0589 525117.4 50
186.0714 317119 30
187.0304 355514 34
187.0429 486759.6 47
187.0668 1393480.6 134
188.0145 1001614 96
188.0257 247462.8 23
188.0383 80235.8 7
188.0508 442006.7 42
188.0745 94375.2 9
189.0461 1404104.1 135
189.0825 213562.2 20
190.0412 243465.1 23
190.0665 46268.3 4
191.0614 93427.3 9
193.0762 249229.9 24
194.0613 73355.5 7
195.0192 58803.8 5
195.0309 162951.7969 15
195.0556 329921.9 31
195.092 150303.6 14
197.0711 214647.6 20
199.0668 212119.9 20
200.0507 587092.6 56
200.0747 239931.4 23
201.046 55557.1 5
201.0588 705852.3 68
201.0823 980294.6 94
202.0306 51904.4 5
202.0665 755534.2 73
202.0903 66436.3 6
203.0617 2856976.8 276
205.0767 255651.5 24
206.0252 203352.9 19
208.0871 209350.6 20
209.0713 246878.7 23
211.0667 57300.5 5
215.0253 1103715.1 106
215.0616 674267.8 65
217.0412 79100.4 7
227.0622 74305.8 7
229.0775 597030 57
233.0362 158059.7 15
243.0568 71010.1 6
//
