ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP007260
RECORD_TITLE: (6R)-6-(TERT-BUTYLDIMETHYLSILYLOXY)-8-PIVALOYLOXY-2-METHYLOCT-2-ENE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: ITO S, DEPT. OF CHEM., TOHOKU UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: (6R)-6-(TERT-BUTYLDIMETHYLSILYLOXY)-8-PIVALOYLOXY-2-METHYLOCT-2-ENE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₂₀H₄₀O₃Si
CH$EXACT_MASS: 356.27467
CH$SMILES: CC(C)=CCCC([H])(CCOC(=O)C(C)(C)C)O[Si](C)(C)C(C)(C)C
CH$IUPAC: InChI=1S/C20H40O3Si/c1-16(2)12-11-13-17(23-24(9,10)20(6,7)8)14-15-22-18(21)19(3,4)5/h12,17H,11,13-15H2,1-10H3/t17-/m1/s1
CH$LINK: INCHIKEY USNUDOVSPZLAND-QGZVFWFLSA-N

AC$INSTRUMENT: HITACHI M-52
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 25 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0a4i-9700000000-1d463517b3dbc324ca1e
PK$NUM_PEAK: 35
PK$PEAK: m/z int. rel.int.
  40 1.8 18
  41 6.3 63
  43 5 50
  55 0.18 2
  56 2.9 29
  57 99.99 999
  58 6.1 61
  67 1.21 12
  69 5.3 53
  73 2.4 24
  75 4 40
  79 0.18 2
  81 9.2 92
  85 16.1 161
  95 4 40
  107 1.06 11
  115 2.6 26
  121 5 50
  122 12.1 121
  123 6.63 66
  124 6.3 63
  129 1.8 18
  144 3.4 34
  157 0.24 2
  159 78.2 782
  160 10.6 106
  161 4.2 42
  171 0.9 9
  177 2.4 24
  213 4 40
  224 1.8 18
  227 0.26 3
  299 5.3 53
  300 1.6 16
  301 0.6 6
//