ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP009918
RECORD_TITLE: ACETOPHENONE 2-METHOXYCARBONYLPHENYLHYDRAZONE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: KURARAY CO., LTD.
LICENSE: CC BY-NC-SA

CH$NAME: ACETOPHENONE 2-METHOXYCARBONYLPHENYLHYDRAZONE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₆H₁₆N₂O₂
CH$EXACT_MASS: 268.12118
CH$SMILES: COC(=O)c(c2)c(ccc2)NN=C(C)c(c1)cccc1
CH$IUPAC: InChI=1S/C16H16N2O2/c1-12(13-8-4-3-5-9-13)17-18-15-11-7-6-10-14(15)16(19)20-2/h3-11,18H,1-2H3/b17-12-
CH$LINK: INCHIKEY GMSDKZMVKPYFOV-ATVHPVEESA-N

AC$INSTRUMENT: JEOL JMS-D-300
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-00n0-5590000000-7949f8e2c9baa967d3cf
PK$NUM_PEAK: 72
PK$PEAK: m/z int. rel.int.
  26 0.2 2
  27 2.6 26
  28 3.4 34
  38 0.17 2
  39 8.6 86
  40 0.3 3
  42 2.8 28
  50 0.52 5
  51 21 210
  52 5.2 52
  53 1.4 14
  59 0.1 1
  62 1.2 12
  63 6.9 69
  64 5.9 59
  65 0.72 7
  66 0.3 3
  74 0.3 3
  75 1.7 17
  76 0.59 6
  77 55.7 557
  78 16.6 166
  79 2.4 24
  84 0.29 3
  89 1.6 16
  90 6.9 69
  91 8.8 88
  92 0.97 10
  93 1 10
  102 2.8 28
  103 37.9 379
  104 1.09 11
  105 12.1 121
  106 1.7 17
  118 14.7 147
  119 0.81 8
  120 2.9 29
  129 0.3 3
  131 0.3 3
  133 0.17 2
  134 35.9 359
  135 6 60
  136 0.3 3
  139 0.16 2
  140 0.5 5
  150 0.5 5
  151 1.6 16
  152 0.03 0
  165 9.1 91
  166 4.3 43
  167 3.4 34
  168 0.14 1
  178 2.9 29
  179 2.4 24
  180 1.2 12
  191 0.02 0
  193 4 40
  194 3.6 36
  195 1.2 12
  206 0.07 1
  207 10.3 103
  208 8.8 88
  209 2.6 26
  220 0.1 1
  221 2.2 22
  235 99.99 999
  236 34.3 343
  237 0.41 4
  267 1.2 12
  268 88.1 881
  269 15.9 159
  270 1.6 16
//