ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP010703
RECORD_TITLE: METHYL TRIACETYL-ALPHA-L-RHAMNOPYRANOSIDE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: EGUCHI S, FAC. OF SCIENCE, HIROSHIMA UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: METHYL TRIACETYL-ALPHA-L-RHAMNOPYRANOSIDE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₃H₂₀O₈
CH$EXACT_MASS: 304.11582
CH$SMILES: CC(=O)OC([H])(C([H])(C)1)C([H])(OC(C)=O)C([H])(OC(C)=O)C([H])(OC)O1
CH$IUPAC: InChI=1S/C13H20O8/c1-6-10(19-7(2)14)11(20-8(3)15)12(21-9(4)16)13(17-5)18-6/h6,10-13H,1-5H3/t6-,10?,11-,12+,13?/m0/s1
CH$LINK: INCHIKEY RTVWBDNQHISFHI-WBLBWYBMSA-N

AC$INSTRUMENT: HITACHI RMU-6L
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0ktf-6900000000-5ddff878a628c25be041
PK$NUM_PEAK: 90
PK$PEAK: m/z int. rel.int.
  41 6 60
  42 5 50
  43 99.99 999
  44 1.2 12
  45 13 130
  47 6 60
  48 3 30
  49 0.2 2
  50 1 10
  53 2.3 23
  54 1.5 15
  55 0.6 6
  56 2 20
  57 7 70
  58 8 80
  59 0.4 4
  60 5 50
  61 8 80
  69 5 50
  70 0.3 3
  71 31 310
  72 4 40
  73 10 100
  74 4.6 46
  75 3 30
  81 2 20
  82 13 130
  83 3.5 35
  84 9 90
  85 19 190
  86 2 20
  87 3.4 34
  88 3 30
  89 1.5 15
  95 1 10
  96 1.3 13
  97 3 30
  98 5 50
  99 26 260
  100 2.8 28
  101 10 100
  102 43 430
  103 28 280
  104 0.2 2
  110 2 20
  111 18 180
  112 2.5 25
  113 2.8 28
  114 4 40
  115 61 610
  116 21 210
  117 0.5 5
  118 1 10
  120 1 10
  125 3.5 35
  126 0.8 8
  127 4.3 43
  128 1.8 18
  129 12 120
  130 0.12 1
  131 1 10
  140 16 160
  141 3 30
  142 2.5 25
  143 7 70
  144 26 260
  145 12 120
  146 0.13 1
  153 15 150
  156 1.8 18
  157 84 840
  158 1.2 12
  159 2.5 25
  171 4 40
  172 0.8 8
  184 3.7 37
  185 19 190
  186 2.3 23
  187 2.5 25
  188 0.1 1
  200 3 30
  201 2.5 25
  202 0.8 8
  212 0.1 1
  213 1.5 15
  217 2.5 25
  244 2.7 27
  245 0.08 1
  273 10 100
  274 1.5 15
//