ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP011404
RECORD_TITLE: 2-METHYL-4-(TRIMETHYLSILYL)METHYL-5-HEXEN-3-ONE; CI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: HISAHIRO HAGIWARA, INSTITUTE FOR CHEMICAL REACTION SCIENCE TOHOKU UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: 2-METHYL-4-(TRIMETHYLSILYL)METHYL-5-HEXEN-3-ONE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₁H₂₂OSi
CH$EXACT_MASS: 198.14399
CH$SMILES: C=CC(C(=O)C(C)C)C[Si](C)(C)C
CH$IUPAC: InChI=1S/C11H22OSi/c1-7-10(8-13(4,5)6)11(12)9(2)3/h7,9-10H,1,8H2,2-6H3
CH$LINK: INCHIKEY IRXDIOWOELNKOQ-UHFFFAOYSA-N

AC$INSTRUMENT: JEOL JMS-DX-300
AC$INSTRUMENT_TYPE: CI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV
AC$MASS_SPECTROMETRY: REAGENT_GAS METHANE

PK$SPLASH: splash10-053r-1900000000-708f21b788415aa9b0ff
PK$NUM_PEAK: 28
PK$PEAK: m/z int. rel.int.
  55 2.8 28
  67 4.5 45
  71 25.1 251
  73 13.6 136
  75 4.7 47
  91 5.3 53
  109 81.1 811
  110 8.7 87
  117 6.8 68
  119 3.2 32
  127 4.3 43
  129 13.8 138
  130 2 20
  131 2.9 29
  143 2.5 25
  145 2.6 26
  147 6.2 62
  155 6.9 69
  157 3.1 31
  183 99.99 999
  184 18.8 188
  185 6.8 68
  198 3.3 33
  199 55.1 551
  200 10.7 107
  201 3.1 31
  239 2 20
  271 6.9 69
//